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3.7.13.5.11. Remove a Service from a Zone by Editing XML files
An editor running with root privileges is required to edit the XML zone files. To view the files for previously configured zones, enter the following command as root:
~]# ls /etc/firewalld/zones/
external.xml  public.xml  work.xml
To remove a service from a zone, for example to remove SMTP from the work zone, use an editor with root privileges to edit the /etc/firewalld/zones/work.xml file to remove the following line:
<service name="smtp"/>
If no other changes have been made to the work.xml file, it can be removed and firewalld will use the default /usr/lib/firewalld/zones/work.xml configuration file after the next reload or system boot.